D. Thoenes's Chemical Reactor Development: From Laboratory Synthesis to PDF

By D. Thoenes

ISBN-10: 9048144469

ISBN-13: 9789048144464

ISBN-10: 940158382X

ISBN-13: 9789401583824

Chemical Reactor Development is written basically for chemists and chemical engineers who're taken with the advance of a chemical synthesis from the laboratory bench scale, the place the 1st winning experiments are played, to the layout table, the place the 1st advertisement reactor is conceived. it's also written for these chemists and chemical engineers who're all for the extra improvement of a chemical procedure with the target of bettering the functionality of an present business plant, in addition to for college students of chemistry and chemical engineering.
partially I, the `how' and the `why' of chemical response engineering are defined, fairly in case you aren't accustomed to this region. half II bargains with the consequences of a few actual phenomena at the end result of chemical reactions, similar to micro and meso-mixing and place of dwelling time distribution, mass move among stages, and the formation of one other part, comparable to in precipitations. those scale-dependent results usually are not purely vital in view of the conversion of chemical reactions, but additionally in regards to the selectivity, and in relation to reliable items, to their morphology. partially III, a few purposes are handled in a normal method, together with natural syntheses, the conversion and formation of inorganic solids, catalytic approaches and polymerizations. The final bankruptcy offers a evaluation of the significance of the selectivity for product caliber and for the purity of waste streams.
For study chemists and chemical engineers whose paintings comprises chemical response engineering. The publication can also be compatible as a supplementary graduate textual content.

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Extra resources for Chemical Reactor Development: From Laboratory Synthesis to Industrial Production

Example text

Even if there are small deviations from the ideal behaviour, both strirred and tubular reactors can be designed with sufficient confidence. The scale-up problems become much more difficult if the large scale reactor differs considerably from these ideal models. Notorious examples are fluidized bed reactors without internals, stirred tanks where the macro mixing is rate determining, and reactors filled with solid material where large temperature gradients exist, such as coke ovens and blast furnaces, and some catalytic gas-phase processes.

9), 31 MODELS FOR IDEAL SINGLE-PHASE REACfORS and we fmd after integration a relation for the degree of conversion as a function of time, for a second order reaction in an ideal batch reactor, and for varying density, as shown in eq. 23) kc t = 2. 3 for three values of co. We can see that the time to reach a given degree of eonversion inereases for higher values of co. 80 ... 3. The degree 0/ conversion 0/ a second order batch reaction. 5 (volume halves on complete conversion); according to eq.

What is the reaction order? The relative concentrations are plotted versus time, and a smooth curve is drawn through the five points. The inclination of the curve is measured in all the five points, and plotted in another graph versus the concentration. Prom the slope of this line we [md the reaction order = 2; see eqs. 12). 1. 5, 1 or 2. Another case of practical importance is the second order reaction, described by eqs. 4), carried out in a batch reactor with a known excess of one of the reactants, say reactant B.

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Chemical Reactor Development: From Laboratory Synthesis to Industrial Production by D. Thoenes

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