Download e-book for iPad: Carbon materials for catalysis by Philippe Serp

By Philippe Serp

ISBN-10: 047017885X

ISBN-13: 9780470178850

This is often the 1st complete ebook overlaying all facets of using carbonaceous fabrics in heterogeneous catalysis. It covers the practise and characterization of carbon helps and carbon-supported catalysts; carbon floor chemistry in catalysis; the outline of catalytic, photo-catalytic, or electro-catalytic reactions, together with the advance of latest carbon fabrics comparable to carbon xerogels, aerogels, or carbon nanotubes; and new carbon-based fabrics in catalytic or adsorption techniques. this can be a optimal reference for carbon, inorganic, and actual chemists, fabrics scientists and engineers, chemical engineers, and others.

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11 shows a proposed surface chemistry that highlights the electrontransfer possibilities both at graphene edges and within the basal plane. Its main features are (1) the existence of free edge sites, and (2) the notion that the basal plane is not as chemically inert as is often envisaged, due to the presence of (delocalized) unpaired electrons, a common consequence of the presence of an uneven number of C–H bonds in the condensed polyaromatic structure of graphene. A detailed justification for the existence of carbenelike zigzag edge sites and carbynelike armchair edge sites has been provided elsewhere [80].

But there is no compelling evidence for the dominant, or even substantial, presence of curved sp2 nanostructure in soot or carbon black. ” Among the many is none other than Donnet [45,46], a leading authority on carbon blacks [47]. An authoritative summary of this exciting episode of carbon physical chemistry research has been offered by Curl in his Nobel award lecture [48]: “[T]he conjecture that soot consists of spiraling spheroidal shells is probably wrong. However, I think it likely that there is some more subtle connection between the curvature introduced by five-membered rings and soot formation.

E. Gibbs, H. Liander, Trans. Faraday Soc. 26 (1930) 656. W. J. A. Ross, J. Chem. Soc. (1965) 240. F. , Prentice Hall, Upper Saddle River, NJ, 1996. H. -D. F¨orsterling, Principles of Physical Chemistry: Understanding Molecules, Molecular Assemblies, Supramolecular Machines, Wiley, Chichester, UK, 2000. J. Steed, J. Atwood, Supramolecular Chemistry, Wiley, Chichester, UK, 2000. R. Radovic, in F. B´eguin, E. , Electrochemistry of Carbon Materials, Taylor & Francis, (CRC Press), Boca Raton, FL, in press.

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Carbon materials for catalysis by Philippe Serp


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